As a form of visual communication, clothing color is inseparable from the expression of psychological emotion. Through the study of related theories such as psychology, color science and aesthetics, combined with the particularity of film and clothing figurative, the article analyzes the silent expression of clothing color in the movie. Focusing on the method of shaping the characters in costumes in Marie Antoinette, through the use of regular color concept and psychological knowledge, deeply analyze the changes of people's psychological emotions, and use their characteristics to make design schemes for the film. The color matching of the clothing provides a reference.